Effects of particle size and dispersion methods of In2O3‐SnO2 mixed powders on the sintering properties of indium tin oxide ceramics

Three group samples were used to investigate the effects of particle size and dispersion methods of In₂O₃‐SnO₂ mixed powders on the sintering properties of ITO ceramics by BET, SEM, XRD, and EPMA, etc. High‐density (99.8% of TD) ITO ceramics, with dimensions of 350 × 250 × 8 mm³ for the industrial application, were obtained by the mixed powders of In₂O₃ calcined at 1000°C and SnO₂ with BET 6.0 ± 0.5 m²/g and collocation use of ball mill for 300 minutes, stirred mill for 60 minutes, and sand mill for 3 minutes. The results indicate that: (i) the larger the SnO₂/In₂O₃ particle size ratio, the higher the density of ITO ceramics, (ii) the dispersion of mechanical ball‐mill methods for nanosized In₂O₃ and SnO₂ powders is beneficial to the densification and structural homogeneity, and (iii) the smaller the relative grain size, the more uniform the distribution of grain size.     

Experimental investigation of different morphology textured ceramic tools by in-situ formed for the dry cutting

Surface texture is considered an important measure to improve the cutting performance of a tool. In this study, we have prepared three types of textured and conventional tools on the rake face by an in-situ formed method. During the experiment, the best parameters of three types of textured tools were selected for dry cutting AISI 1045 steel at different cutting speeds. Cutting forces, cutting temperatures, workpiece surface roughness, and tool wear were measured during the cutting process. The results showed that textured tools have significantly reduced cutting force, cutting temperature, and tool wear, and the roughness of the workpiece was improved compared with the conventional tool. The micro-pit texture tool has less stress contact region than the micro-groove width texture tool, but the micro-groove width texture tool exhibiting the best cutting performance. This investigation clearly showed that the textured tool prepared by the in-situ formed method has improved cutting performance.     

缓冷出口温度对连续退火SPCC冷轧薄板屈服强度的影响

研究了缓冷出口温度对连续退火SPCC冷轧薄板组织和屈服强度的影响。结果表明:连续退火SPCC冷轧薄板的组织由等轴的铁素体晶粒和晶界处的块状渗碳体及晶粒内的颗粒状渗碳体组成。随着缓冷出口温度从680 ℃提高至700 ℃,平均晶粒尺寸从10.1 μm增加至12.5 μm;此外,提高缓冷出口温度还能够抑制晶界处块状渗碳体的形成,促进晶粒内细小渗碳体更加细小弥散的析出。当缓冷出口温度从680 ℃提高至700 ℃时,冷轧薄板的屈服强度约降低了28 MPa。     

焦油渣性质评价与加氢裂化性能研究

焦油渣中挥发的有机烃类化合物易造成较为严重的环境问题,对焦油渣的较高处理成本导致其仍未能被有效处理与合理利用,因而有必要对焦油渣的性质和高附加值利用进行研究。对2种不同煤炭加工技术在生产中获得的焦油渣进行性质分析,并对焦油渣在高温高压下加氢裂化性能进行研究,即加氢裂化反应后得到的气体产物采用组分分析后得到气产率,对液固产物进行萃取分离后可得到不同条件下加氢裂化反应的氢耗、气产率、液相物产率和四氢呋喃不溶物的转化率。通过对不同加工途径所产生焦油渣的性质进行研究可发现,大多数焦油渣含有10%以上的水分和20%以上的焦油,焦化和气化工艺所产焦油渣中的灰分较高而中低温热解焦油渣的灰分相对较低,且其甲苯不溶物和四氢呋喃不溶物均高于中低温热解焦油渣。由2种典型焦油渣在不同的工艺条件、催化剂和供氢介质作用下加氢裂化的实验结果表明:通过改变工艺条件和催化剂,中低温热解焦油渣中95%以上的组分均能被裂解为轻质化合物,气化焦油渣中四氢呋喃可溶解的组分也能够进一步被裂解为轻质组分,而其固含物却难以再被进一步地裂解。     

Carborane and cyanine conjugated galactose targeted amphiphilic copolymers for potential near infrared imaging-guided boron neutron capture therapy (BNCT)

Near infrared fluorescent galactose targeted glycopolymer containing m-carborane has been synthesized through ring open and atom transfer radical polymerization, followed by post-functionalization with a cyanine NIR dye. The copolymer could self-assemble into micelles which work as a potential agent for imaging-guided boron neutron capture therapy. The NIR micelles revealed no cytotoxicity for HepG2 cells. An enhanced and fast endocytosis due to the specific interaction between the HepG2 cells and the glycopolymer could be traced by fluorescence microscopy, and the bioimaging makes it possible to trace the nanoparticles and provides information where and when the neutron irradiation should be triggered.     

综放工作面风量及采空区漏风定量检测

通过对中煤塔山煤矿30509综放工作面采空区漏风及有害气体分析的研究，总结了通过定量连续释放SF₆示踪气体，来检测工作面风量与采空区漏风的方法，测定了沿工作面采空区的漏风分布及漏风流线的深度。采用定时测量法，确定了30509工作面随工作面不断推进，与对应地表发生了导通现象；采用定量测量法，确定了内部漏风量和外部漏风量较大，对综采工作面采空区自然发火存在较大风险，同时提出了防范措施，为减少综放工作面采空区漏风、防止自然发火的发生提供了参考。     

可控中子孔隙度测井仪器设计

源距与屏蔽体厚度是直接影响可控中子孔隙度测井仪器测量准确性的重要参数。源距不仅影响测井仪器的测量误差，还影响测井仪器对地层孔隙度的灵敏度。屏蔽体厚度是保障测井响应完全反映地层的重要参数。从灵敏度、屏蔽率以及误差3个方面确定可控中子孔隙度测井仪器的源距与屏蔽体厚度。研究结果表明:近探测器源距越小，测井仪器灵敏度越高；近远探测器的间距对测量误差的影响随间距的增大，先减小再增大；当屏蔽率在70%以上且屏蔽率随厚度的变化较为缓慢时的屏蔽体厚度可作为屏蔽体最低厚度。